Synthesis of non-agglomerating submicron/nano-Yb2Si2O7 powders by a carbon-coated coprecipitation method

We herein report a novel carbon-coated coprecipitation method to synthesize non-agglomerating submicron/nano-β-Yb₂Si₂O₇ powders. Yb(C₂H₃O₂)₃·4H₂O and silica sol (alkaline) were chosen as the ytterbium source and silicon source, respectively. A carbon surface layer is processed using sucrose as carbon source to hinder the contact and sintering of β-Yb₂Si₂O₇ particles during heat treatment under a protective atmosphere, and then the carbon layer could be completely removed by inletting air at 900°C during cooling process. The as-synthesized Yb₂Si₂O₇ powders demonstrate an average size of 271 nm with a narrow distribution of 142–531 nm. The results show that the carbon layer could successfully solve the severe agglomeration or sintering of nanometer β-Yb₂Si₂O₇ particles during the calcination process. The as-developed carbon-coated coprecipitation technique is an effective method to fabricate high purity submicron/nano-Yb₂Si₂O₇ powders.     

粗碲粉加压氧化浸出工艺研究

针对上游工序发生改变，研究了采用加压氧化浸出工艺处理粗碲粉。采用单因素试验考察了液固比、游离碱度、反应压力、反应温度、反应时间对浸出效果的影响，确定最佳工艺条件为：液固比10，游离碱浓度40g/L，反应压力0.8MPa，反应温度75℃，氧化时间2h。试验结果表明碲的浸出率可达95.45％，金银富集在20倍以上。     

The influence of FeNi nanoparticles on the microstructures and soft magnetic properties of FeSi soft magnetic composites

In this work, a new type of FeSi/FeNi soft magnetic powder core (SMPC) was successfully fabricated by coating FeNi nanoparticles on the surface of FeSi micrometer powder. The effects of different contents of FeNi nanoparticles on the micromorphology, internal structures, and soft magnetic properties of SMPCs were studied. The results show that FeNi nanoparticles adhere to the surface of FeSi powder, which can effectively fill the air gap between FeSi powder and is beneficial to the compaction of the powder cores during the pressing process. Thus, the density of the SMPCs is increased. Compared to FeSi SMPCs, the comprehensive soft magnetic properties of FeSi/FeNi SMPCs have been greatly improved. When adding 15 wt% FeNi nanoparticles, the SMPCs exhibit excellent magnetic properties with high effective permeability (increased by 43.8 %) and low core loss (decreased by 22.1 %). The high performance FeSi/FeNi SMPCs prepared in this work are expected to be widely used in power choke coils, uninterruptible power supplies, and boosts and inverter inductors.     

涂布级超细大理岩粉制备及其特征

以广东茂名某地-325目大理岩粉为原料。采用湿法搅拌磨超细加工工艺，讨论了磨矿浓度、磨矿介质配比、分散剂种类、用量、转速和时间等对磨矿粒度的影响。在最优工艺条件下，试验产品粒度特征是：-2μm〉90％、D90〈2μm，SEM形貌观察为板状或片状，涂布后各项物理指标达到了铜版纸要求的标准。     

超细Nb_20_5粉末的研制

对采用均匀沉淀法制备陶瓷电容器级(平均粒径为0.1-0.2μm的超细粉末)Nb2O5粉末的最佳工艺条件进行了探讨,研究了均匀沉淀过程中,反应温度、沉淀终点pH值、反应物浓度、脱水剂和添加剂以及焙烧温度对Nb(OH)5粉体粒度分布及粒径的影响。利用TG-DTA、SEM、XRD、比表面积测试仪(BET)和CILAS粒度测试仪进行了测定,结果表明:当H2NbOF5浓度在0.2~0.4M时,以NH3·H2O作沉淀剂,用乙醇、丙酮等作脱水剂,所获沉淀在80~100℃干燥后,制备的Nb(OH)5粉体粒度均匀且分布窄,其平均粒径为0.07 μm,经700℃焙烧后,可制得粒度分布窄、团聚少、比表面积为14.44 m2/g、平均粒径为0.1 μm,且纯度>99.95%的陶瓷电容器级Nb2O5微粉体。该方法具有设备简单、工艺流程短、污染小,产品纯度高等特点。     

表面活性剂对电解锌粉形貌的影响

研究氯化铵体系电解制备超细锌粉时,三种典型的表面活性剂对槽电压,锌粉沉积状态和锌粉颗粒大小和形态的影响.结果表明,在锌离子浓度为32g/L.电解液温度为60℃时,非离子表面活性剂吐温-80可以使锌粉颗粒均匀分散,表面活性剂的加入对槽电压影响不大.     

石灰石资源的开发利用

本文比较系统地介绍了我国优势资源石灰石的性质，一般用途和矿床的工业要求，列举了主要产品１７种；简述了１０种（类）钙盐产品的工业生产方法，并绘出了工艺流程示意图；对当前石灰石利用前景和可能开发方向提出了参考建议，可供石灰石储量丰富地区有关企业和当地政府在规划开发资源时作参考。     

去除水中黄药的试验研究

为给选矿废水中残余黄药的去除提供依据，分别采用自然曝晒法、漂白粉氧化法、酸化分解法、亚铁沉淀法、活性炭吸附法对配制的黄药水溶液进行了黄药降解试验，结果表明，以上诸方法均能较彻底地去除溶液中的黄药，使水中的黄原酸盐浓度达到国家排放标准。其中亚铁沉淀法、漂白粉氧化法药剂来源容易，价格便宜，工艺简单，效果好，较适合处理含黄药选矿废水。     

对武安高岭土除铁工艺研究

河北武安硬质高岭土粉含Fe2O31.23%，经高梯度磁选后降至0.77%，再用Na2S2O3进行还原溶解后降至0.62%，白度提高了13％，本文介绍了流程及条件试验过程和结果。